Synthesis and Characterization of a Novel Energetic Complex [Cd (DAT) 6](NO3) 2 (DAT= 1, 5??diamino??tetrazole) with High Nitrogen Content

…, YJ Shu, TL Zhang, L Yang, PP Power

Index: Zhang, Jian-Guo; Li, Jing-Yu; Zang, Yan; Shu, Yuan-Jie; Zhang, Tong-Lai; Yang, Li; Power, Philip P. Zeitschrift fur Anorganische und Allgemeine Chemie, 2010 , vol. 636, # 6 p. 1147 - 1151

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Citation Number: 5

Abstract

Abstract The novel high nitrogen-containing energetic complex [Cd (DAT) 6](NO 3) 2 was synthesized by reaction of Cd (NO 3) 2· 6H 2 O with 1, 5-diamino-tetrazole (DAT). It was characterized by elemental analysis, FT-IR spectroscopy and single-crystal X-ray diffraction analysis. The central Cd 2+ ion is coordinated by six nitrogen atoms from six DAT ligand molecules to form a hexacoordinate distorted octahedral compound. The [Cd (DAT) 6](NO ...