Journal of the American Chemical Society

Electronic excitation energy partitioning in dissymmetric dioxetane thermolyses. The absolute chemiluminescence yields and triplet to singlet excited state ratios for 3- …

KA Horn, GB Schuster

Index: Horn,K.A.; Schuster,G.B. Journal of the American Chemical Society, 1978 , vol. 100, # 21 p. 6649 - 6656

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Citation Number: 19

Abstract

23, 408 (1978); J. Polym. Sci., Polym. Lett. Ed., 16, 335 (1978). on a single sample preannealed for 14 h at 333 K [gt)-0.032; T,,,-375 K]. They incorrectly concluded that this indicated the presence of a" new high temperature phase which acts as the monomer form for the bulk of the reaction". This is clearly not the case since T,,, increases monotonically with conversion. This increase is undoubtedly a consequence of the fact that there is solid ...