Interaction of perfluorinated α-fluorosulfatocarbonyl compounds with nucleophilic reagents

NI Delyagina, EA Avetisyan, VM Rogovik…

Index: Delyagina, N. I.; Avetisyan, E. A.; Rogovik, V. M.; Cherstkov, V. F.; Sterlin, S. R.; German, L. S. Journal of Fluorine Chemistry, 1993 , vol. 65, # 3 p. 217 - 222

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Abstract

Abstract α-Perfluorosulfatoperfluorocarbonyl compounds interact with alkaline metals halogenides to form the corresponding α-halo derivatives as a result of the direct nucleophilic substitution of the FSO 3 group. Through the action of halogenide anions on perfluorinated α, β-bis-fluorosulfatocarbonyl compounds, substitution by halogen of the FSO 3 group in the α-position to the carbonyl takes place. However, the FSO 3 group in the β- ...