Rearrangements and other reactions of benzyl-type-quaternary ammonium ions with certain organolithium reagents

KP Klein, DN Van Eenam…

Index: Klein,K.P. et al. Journal of Organic Chemistry, 1967 , vol. 32, p. 1155 - 1160

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Citation Number: 13

Abstract

The benzyltrimethylammonium ion reacted with n-butyllithium in ether-hexane to form mainly the orthosubstitution rearrangement product, usually a considerable amount of a Stevens 1, 2shift product and smaller amounts of another Stevens product, three higher boiling amines, and a displacement product. The benzhydryltrimethylammonium ion reacted with this reagent to afford mainly a Stevens 1, Bshift product, a considerable amount of the ortho- ...

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