Journal of Organometallic Chemistry

Un nouvel aspect de la reactivite des trihalogenomethyltrialkyletains: l'addition aux aldehydes

C Furet, C Servens, M Pereyre

Index: Furet,C. et al. Journal of Organometallic Chemistry, 1975 , vol. 102, p. 423 - 430

Full Text: HTML

Citation Number: 10

Abstract

Abstract Trichloromethyl-and tribromomethyl-tributyltin give adducts with aldehydes. On acidolysis the corresponding trichloromethyl-and tribromomethylcarbinols are obtained in good yields. The stereochemistry of the addition reaction with hydratropic aldehyde was investigated and the substituent effects were determined by means of competitive experiments with substituted benzaldehydes. The inefficiency of free radical reaction ...

Related Articles:

An unusual reaction of trichloromethane with acylals in the interphase catalysis conditions.

[Kryshtal, G. V.; Bogdanov, V. S.; Yanovskaya, L. A. Tetrahedron Letters, 1982 , vol. 23, # 35 p. 3607 - 3610]

β??Siloxy?螃窿?haloketones through Highly Diastereoselective Single and Double Mukaiyama Aldol Reactions

[Saadi, Jakub; Yamamoto, Hisashi Chemistry - A European Journal, 2013 , vol. 19, # 12 p. 3842 - 3845]

Decarboxylative Trichloromethylation of Aromatic Aldehydes and Its Applications in Continuous Flow

[Benner, Jill P.; Gill, G. Bryon; Parrott, Stephen J.; Wallace, Brian Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 3 p. 291 - 313]

Decarboxylative Trichloromethylation of Aromatic Aldehydes and Its Applications in Continuous Flow

[Benner, Jill P.; Gill, G. Bryon; Parrott, Stephen J.; Wallace, Brian Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 3 p. 291 - 313]

More Articles...