Synthesis, Crystal Structure, and Characterization of a Novel Supramolecular Cluster Compound [(BPE) 3 (WOS3Cu3Br4) 2]

…, H Chen, C Chen, Y Chen, Z Zhang…

Index: Cao, Ting; Chen, Hong; Chen, Chunguang; Chen, Yuqing; Zhang, Zhenhua; Niu, Yun-Yin Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2013 , vol. 43, # 4 p. 417 - 419

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Abstract

Orange-yellow crystals of the title compound were obtained from the reaction of [NH4] 2 [WO2S2], CuI, and bpe· Br2 (1: 3: 2) in DMF solution. And the crystal system is trigonal, space group P–3 c 1, with unit cell parameters a= 13.9730 (15) Å, b= 13.9730 Å, c= 18.1365 (19) Å, and Z= 2. This cluster compound possesses a wheel-shaped supramolecular structure containing tetranuclear cluster core. Supplemental materials are available for ...