Synthesis and transformations of 1-(azidophenyl)-1H-tetrazoles

NT Pokhodylo, VS Matiichuk, ND Obushak

Index: Pokhodylo; Matiichuk; Obushak Russian Journal of Organic Chemistry, 2010 , vol. 46, # 4 p. 556 - 560

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Citation Number: 3

Abstract

Abstract Diazotization of 1-(aminophenyl)-1 H-tetrazoles and subsequent treatment of the diazonium salts with sodium azide gave 1-(azidophenyl)-1 H-tetrazoles which were brought into cyclization with ethyl acetoacetate and cyanoacetanilide to obtain 1, 2, 3-triazole derivatives. Under these conditions, the tetrazole ring may undergo cleavage with formation of cyanamide group.

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