A periodonium trifluoromethanesulfonate. An isolable 10-I-4 organoiodine species

DB Dess, JC Martin

Index: Dess, D. B.; Martin, J. C. Journal of the American Chemical Society, 1982 , vol. 104, # 3 p. 902 - 903

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Citation Number: 27

Abstract

C,H,- + F,CCO,C,H, + F,CCO,- + C,H, + C,H6 ... C,H,- + F,CCO,C(CH,), +F,CCO,- + H,C=C(CH ,), + C,H6 -50.0 (11) ... To determine if the exoergicity of reaction 10 would be sufficient to effect the secondary decomposition of F,CCO, - F3C- + C02 observed in the reaction of the ethyl ester, we examined the reaction of C3H5- with the tert-butyl ester, F3CC02C(CH,),. Here, again, a fast pseudo-first-order decay of C3H; was observed (k = (1.3 f 0.1) X cm3 ...