Journal of the American Chemical Society

Cyclic Polyolefins. VIII. Reactions of 6-Hydroxycyclodecanone and Cyclodecan-1, 6-diol p-Toluenesulfonates

AC Cope, G Holzman

Index: Cope; Holzman Journal of the American Chemical Society, 1950 , vol. 72, p. 3062,3065

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Citation Number: 18

Abstract

The oxidation of decalin to trans-9-decalylhydroperoxide (I) was shortened to one and onehalf to two and one-half-hours and the conversion to I was improved to 2.5-3.0% by using a reaction temperature of 130'with periodic addition of benzoyl peroxide as a catalyst. Previously the oxidation had been conducted at 110'for twentyfour hours with no added catalystza (1.4% conversion) and at 70'for two hundred hours with irradiation by ultraviolet ...