The Chemistry of Aliphatic Disulfides. III. 1 Formation of Sulfides During Cleavage by Cyanide Ion2

RG Hiskey, FI Carroll

Index: Hiskey,R.G.; Carroll,F.I. Journal of the American Chemical Society, 1961 , vol. 83, p. 4647 - 4650

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Citation Number: 5

Abstract

Since XI was cleanly produced from I11 and a reasonable material balance could be obtained, this reaction was investigated in more detail. Consideration of the proposed mechanism for nucleophilic cleavage of the sulfur-sulfur bond5J suggested that a reaction between VI and X in the presence of N, N-diphenylcarbamyl chloride should afford the same products obtained from cleavage of 111; however, a similar experiment involving I and ...