Fluoroketones. I

HE Simmons, DW Wiley

Index: Simmons,H.E.; Wiley,D.W. Journal of the American Chemical Society, 1960 , vol. 82, p. 2288 - 2296

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Citation Number: 83

Abstract

Fluoroketones have been shown to be versatile intermediates for the synthesis of new fluorine-containing structures. Ketals of unusual thermal and chemical stability have been prepared by a novel base-promoted ketalization. The synthesis was extended to dioxolanes, dioxanes, oxazolidines, oxathiolanes and their carbonyl-containing analogs. Fluoroketones reacted with diazomethane to give high yields of stable epoxides, and condensed readily ...