Tetrahedron

Phosphorothioates—III: Reactions with phosphorothionyl disulphides with organometallic reagents.

B Miller

Index: Miller,B. Tetrahedron, 1964 , vol. 20, p. 2069 - 2078

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Citation Number: 13

Abstract

Organometallic reagents attack the S S bonds of phosphorothionyl disulphides (V) to give high yields of the corresponding S-substituted phosphorodithioates. S-alkenyl and S-alkynyl phosphorodithioates, previously unknown, were prepared in this manner. No indication of attack at phosphorus atoms, of reduction of S S bonds, or of benzylic rearrangements of the organo-metallic reagents were observed.