Mode of attack of atomic carbon on benzene rings

BM Armstrong, F Zheng, PB Shevlin

Index: Armstrong, Brian M. Journal of the American Chemical Society, 1998 , vol. 120, # 24 p. 6007 - 6011

Full Text: HTML

Citation Number: 23

Abstract

Reaction of arc generated carbon atoms with tert-butylbenzene, 4, gives 3-methyl-3-phenyl- 1-butene, 5, and 1, 1-dimethylindane, 6. Labeling studies and isotope effects demonstrate that 5 results from an insertion into a methyl CH bond followed by 1, 2 hydrogen shift while 6 arises from initial ortho CH insertion followed by intramolecular insertion into a methyl CH bond. When fluoroboric acid is added to the 77 K matrix of 4+ C, tert-butyltropylium ...

Related Articles:

Heterodimerization of olefins. 1. Hydrovinylation reactions of olefins that are amenable to asymmetric catalysis

[RajanBabu; Nomura, Nobuyoshi; Jin, Jian; Nandi, Malay; Park, Haengsoon; Sun, Xiufeng Journal of Organic Chemistry, 2003 , vol. 68, # 22 p. 8431 - 8446]

Metallacarboranes in catalysis. 6. Kinetics and mechanism of alkene hydrogenation and isomerization catalyzed by rhodacarborane clusters. A search for cluster …

[Behnken, Paul E.; Belmont, James A.; Busby, David C.; Delaney, Mark S.; King, Roswell E.; et al. Journal of the American Chemical Society, 1984 , vol. 106, p. 3011 - 3025]

Metallacarboranes in catalysis. 6. Kinetics and mechanism of alkene hydrogenation and isomerization catalyzed by rhodacarborane clusters. A search for cluster …

[Behnken, Paul E.; Belmont, James A.; Busby, David C.; Delaney, Mark S.; King, Roswell E.; et al. Journal of the American Chemical Society, 1984 , vol. 106, p. 3011 - 3025]

Hybrid Birch-Claisen Methodology for arylation at allylic termini: synthesis of (±)-herbertene

[Chandrasekaran, S.; Turner, John V. Tetrahedron Letters, 1982 , vol. 23, # 37 p. 3799 - 3802]

Short Synthesis of Chiral 4??Substituted (S)??Imidazolinium Salts Bearing Sulfonates and Their Use in γ??Selective Reactions of Allylic Halides with Grignard Reagents

[Latham, Christopher M.; Blake, Alexander J.; Lewis, William; Lawrence, Matthew; Woodward, Simon European Journal of Organic Chemistry, 2012 , # 4 p. 699 - 707]

More Articles...