Etude des petits cycles-XLIV: Une voie de synthese des acyl-2 cyclobutanones11Pour une publication préliminaire voir Ref 1.

A Lechevallier, F Huet, JM Conia

Index: Lechevallier, A.; Huet, F.; Conia, J.M. Tetrahedron, 1983 , vol. 39, # 20 p. 3329 - 3336

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Citation Number: 10

Abstract

Organic peracid oxidation of α-cyclopropylidene ketones and acetals substituted in the vinylic position leads to the corresponding oxaspiropentyl ketones and acetals. Esters are also formed from the products of the Baeyer-Villiger oxidation; they are easily removed from the crude product. Unsubstituted oxaspiropentyl ketones are not obtained by this method; they are obtained by oxidation of oxaspiropentyl alcohols (formed by epoxidation of α- ...