Electrosynthesis of unsymmetrical polyaryls by a SRN1-type reaction

P Boy, C Combellas, C Suba…

Index: Boy, P.; Combellas, C.; Suba, C.; Thiebault, A. Journal of Organic Chemistry, 1994 , vol. 59, # 16 p. 4482 - 4489

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Citation Number: 16

Abstract

Unsymmetrical polyaryls are electrosynthesized in liquid ammonia by a single-step Swl reaction in the presence of a redox mediator starting from aromatic halides and 2, 6-di-tert- butyl phenoxide. With monoaryl halides activated by electron-withdrawing substituents (N of pyridyl or quinolyl, trifluoromethyl, cyano, sulfone, ester, ketone, alkyl sulfide, Nf of anilinium), biaryls are obtained in good yields (between 50 and 95%). The yields of ter- ...

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Electrosynthesis of unsymmetrical polyaryls by a SRN1-type reaction

Abstract

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