Tetrahedron

Reaction of phenylcarbene formed from benzaldehyde tosylhydrazone in certain solvents

H Nozaki, R Noyori, K Sisido

Index: Nozaki,H. et al. Tetrahedron, 1964 , vol. 20, p. 1125 - 1132

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Citation Number: 29

Abstract

Treatment of benzaldehyde tosylhydrazone (I) with sodium methoxide in various solvents under irradiation and/or heating yields products arising from phenylcarbene (IV) which is produced by photolytic or pyrolytic decomposition of initially formed phenyldiazomethane (III). Reaction products originating solely from the tosylhydrazone (I) are (VI∼ XI) while those produced by the interaction with solvents are formulated as addition products of (VI) to ...

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