Inorganic chemistry

Direct Measure of Metal–Ligand Bonding Replacing the Tolman Electronic Parameter

D Setiawan, R Kalescky, E Kraka, D Cremer

Index: Goldschmidt; Buss Chemische Berichte, 1897 , vol. 30, p. 2075

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Citation Number: 2

Abstract

... metal center.(7) Typical TEP values for phosphines range from 2111 cm –1 for PF 3 (weak electron donor) to 2056 cm –1 for P(t-butyl ... vanadium,(4) chromium,(9-12) molybdenum,(4, 6, 13-16) tungsten,(4, 9, 16-19) rhenium,(20) iron,(21-28) ruthenium,(29) rhodium,(30-39) iridium ...