Phenyl (fluoro) chlorodisiloxanes

SV Basenko, LE Zelenkov, MG Voronkov…

Index: Basenko; Zelenkov; Voronkov; Albanov Russian Journal of General Chemistry, 2010 , vol. 80, # 2 p. 242 - 244

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Citation Number: 5

Abstract

Abstract Cohydrolysis of phenyltrichlorosilane with phenyl (fluoro) dichloro-and phenyl (difluoro)-chlorosilanes and thermolysis of the formed siloxanes leading to the formation of phenyl (difluoro) chlorosilane are studied. The scheme of thermal decomposition of disiloxanes possessing fluorine atoms in the 1, 3 positions is suggested. The scheme is based on the intermediate formation of an active four-membered cyclic complex closed by ...