Studies on the nitrosation of N??silylated cyclopentenylamines

R Martínez Alvarez, A Sánchez Vázquez…

Index: Alvarez, Roberto Martinez; Vazquez, Angel Sanchez; Hananck, Michael; Subramanian Journal of Physical Organic Chemistry, 1996 , vol. 9, # 4 p. 227 - 233

Full Text: HTML

Citation Number: 1

Abstract

Abstract The diazotization of N-silylated N-methyl-and N-phenylcyclopentenylamines affords products derived from intermediate methyl-and phenyldiazonium ions. However, when this method is applied to N, N-bissilylated cyclopentenylamines, the products obtained do not confirm the formation of a cyclopentenyl cation intermediate.

Related Articles:

Brønsted acid-catalyzed efficient Strecker reaction of ketones, amines and trimethylsilyl cyanide

[Zhang, Guang-Wu; Zheng, Dong-Hua; Nie, Jing; Wang, Teng; Ma, Jun-An Organic and Biomolecular Chemistry, 2010 , vol. 8, # 6 p. 1399 - 1405]

Lewis base-catalyzed three-component Strecker reaction on water. An efficient manifold for the direct α-cyanoamination of ketones and aldehydes

[Cruz-Acosta, Fabio; Santos-Exposito, Alicia; De Armas, Pedro; Garcia-Tellado, Fernando Chemical Communications, 2009 , # 44 p. 6839 - 6841]

Transamination of α-amino nitriles

[Popov; Mokhov; Tankabekyan Russian Journal of Organic Chemistry, 2014 , vol. 50, # 1 p. 21 - 24 Zh. Org. Khim., 2014 , vol. 50, # 1 p. 29 - 32,4]

Application of secondary amines in the synthesis of some new spiro heterocyclic compounds

[Soliman; Sultan; Ellah, Omran Abd; El-Shafei Phosphorus, Sulfur and Silicon and the Related Elements, 2010 , vol. 185, # 7 p. 1301 - 1314]

Transamination of α-amino nitriles

[Popov; Mokhov; Tankabekyan Russian Journal of Organic Chemistry, 2014 , vol. 50, # 1 p. 21 - 24 Zh. Org. Khim., 2014 , vol. 50, # 1 p. 29 - 32,4]

More Articles...