Journal of Organometallic Chemistry

Unexpected chemistry in an attempted generation of a sterically hindered silene

TJ Barton, CR Tully

Index: Barton,T.J.; Tully,C.R. Journal of Organometallic Chemistry, 1979 , vol. 172, p. 11 - 19

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Abstract

Abstract In an attempt to synthesis a silene, stabilizer both electronically and by extreme steric bulk, two things of considerable interest were discovered:(1) perchlorate can function as a uniquely effective leaving group for alkylation on silicon, and (2) stable αhalosilyl carbanions can be generated through the aid of steric bulk.

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