Tetrahedron

Directed Lithiation in Arenetricarbonylchromium (0) Complexes: Assessment of Some Directing Group Specificities and of Electrophilic Quench Efficacies

…, DA Widdowson, R Wilhelm, AJP White, DJ Williams

Index: Sebhat, Iyassu K.; Tan, Yen-Ling; Widdowson, David A.; Wilhelm, Rene; White, Andrew J.P.; Williams, David J. Tetrahedron, 2000 , vol. 56, # 33 p. 6121 - 6134

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Citation Number: 20

Abstract

The synthesis of a series of phenol ethers and 4-triisopropylsilyloxymethylphenol ethers and their η6-tricarbonylchromium (0) complexes are reported. The directed lithiation of these followed by quenching with a series of electrophiles gave access to a wide range of functionalised complexes for use in synthesis.

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