The Journal of Organic Chemistry

Synthesis methods and reactions. Part 134. Preparation of 2-aryladamantanes and 3-aryldiamantanes by improved ionic hydrogenation of the corresponding tertiary …

GA Olah, AH Wu, O Farooq

Index: Olah, George A.; Wu, An-hsiang; Farooq, Omar Journal of Organic Chemistry, 1988 , vol. 53, # 21 p. 5143 - 5145

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Abstract

In the expanding chemistry of hydrocarbon derivatives of adamantane and adamantane analogues, the preparation of tertiary derivatives is accomplished more readily than that of secondary derivativesa2l3 The number of secondary substituted adamantanes is limited since their synthesis could formerly be achieved only by ring-closure reactions in low yield. 2 While preparative procedures for certain secondary derivatives of adamantane are ...

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