Journal of the American Chemical Society

The Schmidt reaction of dialkyl acylphosphonates

M Sprecher, D Kost

Index: Sprecher, Milon; Kost, Daniel Journal of the American Chemical Society, 1994 , vol. 116, # 3 p. 1016 - 1026

Full Text: HTML

Citation Number: 36

Abstract

Abstract: The scope of the Schmidt rearrangement of ketones has been extended to dialkyl acylphosphonates (lla-111). Surprisingly, it was found that lla-lld and llg, in which the acyl moiety was benzoyl alone or benzoyl bearing an electron-attracting or mildly electron- releasing substituent, yielded an overwhelming portion of products resulting from C-to-N migration of the aryl group (N-arylcarbamoylphosphonates, 12, and N-arylformamides, 15) ...

Related Articles:

Syntheses of Spirocyclic Oxindole??Butenolides by Using Three??Component Cycloadditions of Isocyanides, Allenoates, and Isatins

[Li, Jian; Liu, Yuejin; Li, Chunju; Jia, Xueshun Chemistry - A European Journal, 2011 , vol. 17, # 27 p. 7409 - 7413]

Deep eutectic solvent promoted highly efficient synthesis of N, N'-diarylamidines and formamides

[Azizi, Najmadin; Gholibeglo, Elham; Babapour, Mahbobe; Ghafuri, Hossein; Bolourtchian, Seyed Mohammad Comptes Rendus Chimie, 2012 , vol. 15, # 9 p. 768 - 773]

Synthesis and characterization of copper nanoparticles supported on reduced graphene oxide as a highly active and recyclable catalyst for the synthesis of …

[Fakhri, Parisa; Jaleh, Babak; Nasrollahzadeh, Mahmoud Journal of Molecular Catalysis A: Chemical, 2014 , vol. 383-384, p. 17 - 22]

Iron and ruthenium carbonyl catalyzed reductive carbonylation of nitro compounds by sodium methoxide. A significant effect of the metal on the reaction course

[Alper, Howard; Hashem, Khaled E. Journal of the American Chemical Society, 1981 , vol. 103, # 21 p. 6514 - 6515]

A Very Simple, Highly Efficient and Catalyst-free Procedure for the NFormylation of Amines Using Triethyl orthoformate in Water Under Ultrasound-irradiation

[Habibi, Davood; Sahebekhtiari, Hesam; Nasrollahzadeh, Mahmoud; Taghipour, Ahmad Letters in Organic Chemistry, 2013 , vol. 10, # 3 p. 209 - 212]

More Articles...