Journal of Organometallic Chemistry

Reduction of isocyanates and carbodiimides via hydrosilylation

I Ojima, S Inaba

Index: Ojima,I.; Inaba,S. Journal of Organometallic Chemistry, 1977 , vol. 140, p. 97 - 111

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Citation Number: 26

Abstract

Abstract The hydrosilylation of isocyanates is promoted by palladium catalysts and affords N- silylformamides or C-silylamides. The orientation of the reaction depended upon the structure of isocyanates. The reaction of carbodiimides with silicon hydrides, catalyzed by PdCl 2 or (Ph 3 P) 3 RhCl, required higher temperatures to give N-silylformamidines. The adducts obtained in these reactions are precursors to formamides, formamidines, and ...

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