A model for the enantioselective hydrogenation of pyruvate catalysed by alkaloid??modified platinum

…, PA Meheux, SP Griffiths, IM Sutherland…

Index: Simons, K. E.; Meheux, P. A.; Griffiths, S. P.; Sutherland, I. M.; Johnston, P.; et al. Recueil des Travaux Chimiques des Pays-Bas, 1994 , vol. 113, # 10 p. 465 - 474

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Citation Number: 164

Abstract

Abstract A LEED and XPS study of the adsorption of naphthalene, quinoline, and 10, 11- dihydrocinchonidine on Pt (111) at 300K has shown that only naphthalene forms an ordered ad-layer, and that quinoline and the alkaloid adsorb in a disordered state and without decomposition. These experiments do not support the hypothesis of ordered adsorption of alkaloid that forms the basis of the template model for the interpretation of ...

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