Intramolecular Interaction between Hydroxyl Group and π-Electrons. VI. Electronic Effect on the Interaction in ω-Arylalkanols

M Oki, H Iwamura

Index: Oki; Iwamura Bulletin of the Chemical Society of Japan, 1959 , vol. 32, p. 1135,1136

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Citation Number: 47

Abstract

The electronic effect on the intramolecular interaction between the hydroxyl group and the π- electrons of the benzene nucleus was studied with various ω-aryl-alkanols. In 2- arylethanols, introduction of an electron-releasing group into the benzene nucleus gives rise to the shift of the ν O–H absorption maxima to a lower wave number and to greater integrated intensities of the band due to the interacting form, and introduction of an ...