Tetrahedron

Photochemical reactions of allylphenoxide anions

T Kitamura, T Imagawa, M Kawanisi

Index: Kitamura,T. et al. Tetrahedron, 1978 , vol. 34, p. 3451 - 3457

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Citation Number: 21

Abstract

Photochemical behaviour of sodium allylphenoxides 1a–3a was compared with that of corresponding neutral allylphenols 1b–3b, and a striking difference was found in reactivity as well as in course of the reaction. Remarkably higher photoreactivity of allylphenoxide anions, especially that of o-allylphenoxide 1a, is ascribed to the efficiency of electron transfer. The characteristic reaction products derived only from the anions were as follows: ...

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