Palladium-catalyzed alkylations in aqueous media

AL Casalnuovo, JC Calabrese

Index: Casalnuovo, Albert L.; Calabrese, Joseph C. Journal of the American Chemical Society, 1990 , vol. 112, # 11 p. 4324 - 4330

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Citation Number: 405

Abstract

Conclusion. The crystal structures we have reported, in conjunction with prior evidence in the literature, support the notion that macrocyclization of ethylene sulfide oligomers is not an optimal approach to the preorganizational enhancement of transition metal chelation by polythioethers. We are currently exploring alternative strategies that prearrange thioether sulfur atoms for metal ion complexation. juxtapose its two oxygen atoms in a manner that ...

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