Tetrahedron letters

Direct synthesis of carbonyl compounds from THP ethers with IBX in the presence of β-cyclodextrin in water

M Narender, MS Reddy, VP Kumar, YVD Nageswar…

Index: Narender; Reddy, M. Somi; Kumar, V. Pavan; Nageswar; Rao, K. Rama Tetrahedron Letters, 2005 , vol. 46, # 12 p. 1971 - 1973

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Citation Number: 22

Abstract

There are many catalysts reported for the tetrahydropyranylation of alcohols and the cleavage of tetrahydropyranyl ethers to their parent alcohols, 1 but the direct synthesis of carbonyl compounds from tetrahydropyranyl ethers is not widespread in the literature. 2 However, in view of the importance of oxidative deprotection of THP ethers, a number of reagents have been studied such as iron(III) nitrate with clay and montmorillonite K-10, 3 AgBrO 3 and NaBrO 3 in the ...

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