Proximity Effects. XXIX. Solvolysis of Cycloheptenyl Derivatives

AC Cope, CH Park, P Scheiner

Index: Cope,A.C. et al. Journal of the American Chemical Society, 1962 , vol. 84, p. 4862 - 4865

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Citation Number: 22

Abstract

Cycloheptenyl derivatives have been solvolyzed and the products compared with those obtained in the solvolysis of cyclooctenyl derivatives. Solvolysis of Ccyclohepten-1-yl brosylate in either acetic acid or trifluoroacetic acid gave 4-cyclohepten-1-01, 3-cydohepten- 1-01 and 1, 3-and 1, 4cycloheptadiene in contrast to 4-cycloocten-1-yl brosylate which gave bicyclic compounds in addition to the normal products. Acetolysis of 3-cyclohepten-I-yl ...

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