Journal of the American Chemical Society

Mechanistic investigation of the cobalt-catalyzed selective conversion of diallylanilines to quinolines involving CN and CH activations

L Li, WD Jones

Index: Li, Ng; Jones, William D. Journal of the American Chemical Society, 2007 , vol. 129, # 35 p. 10707 - 10713

Full Text: HTML

Citation Number: 55

Abstract

2, 3-Substituted quinolines were readily prepared from diallylanilines in good yields under mild conditions by using Co2 (CO) 8 as catalyst. 1, 2 Regioselectivity has been explored by examining a series of electron-donating and electron-withdrawing functional groups at ortho, meta, and para positions of the diallylanilines. The results show that both steric and electronic effects influence the isolated yields. Electron-withdrawing groups inhibit the ...

Related Articles:

Synthesis of 2, 3-disubstituted quinolines from in situ generated imines and its enamine tautomer under radical cation induced conditions

[Jia, Xiaodong; Peng, Fangfang; Qing, Chang; Huo, Congde; Wang, Yaxin; Wang, Xicun Tetrahedron Letters, 2013 , vol. 54, # 36 p. 4950 - 4952]

Magnetically separable palladium–graphene nanocomposite as heterogeneous catalyst for the synthesis of 2-alkylquinolines via one pot reaction of anilines with …

[Verma, Sanny; Verma, Deepak; Jain, Suman L. Tetrahedron Letters, 2014 , vol. 55, # 15 p. 2406 - 2409]

Ruthenium-catalyzed synthesis of quinolines from anilines and allylammonium chlorides in an aqueous medium via amine exchange reaction

[Cho, Chan Sik; Kim, Joon Seok; Oh, Byoung Ho; Kim, Tae-Jeong; Shim, Sang Chul; Yoon, Nam Sik Tetrahedron, 2000 , vol. 56, # 39 p. 7747 - 7750]

Ruthenium??Catalyzed synthesis of quinolines from anilines and N??allylic compounds by cascade amine exchange reaction??heteroannulation

[Chan Sik Cho; Byoung Ho Oh; Sang Chul Shim; Dae Hee Oh Journal of Heterocyclic Chemistry, 2000 , vol. 37, # 5 p. 1315 - 1320]

Highly enantioselective iridium-catalyzed hydrogenation of 2-benzylquinolines and 2-functionalized and 2, 3-disubstituted quinolines

[Wang, Da-Wei; Wang, Xiao-Bing; Wang, Duo-Sheng; Lu, Sheng-Mei; Zhou, Yong-Gui; Li, Yu-Xue Journal of Organic Chemistry, 2009 , vol. 74, # 7 p. 2780 - 2787]

More Articles...