Biosynthesis of N-methylpelletierine: vindication of a classical biogenetic concept

T Hemscheidt, ID Spenser

Index: Hemscheidt, Thomas; Spenser, Ian D. Journal of the American Chemical Society, 1990 , vol. 112, # 17 p. 6360 - 6363

Full Text: HTML

Citation Number: 20

Abstract

Abstract: The 13C NMR spectrum of a sample of N-methylpelletierine (2), generated biosynthetically from sodium [1, 2, 3, 4-13C4] acetoacetate in Sedum sarmentosum Bunge, shows that the C3 side chain of the alkaloid is derived as an intact unit from the C4 precursor. The" C NMR spectrum of a sample of the alkaloid, biosynthetically derived from sodium [1, 2-I3C2] acetate, shows that it is the-COCH3 unit and not the-CH2CO-unit of the ...

Related Articles:

A new efficient synthesis of β-aminoketones via Δ 4-isoxazolines.

[Mancuso, Vincent; Hootele, Claude Tetrahedron Letters, 1988 , vol. 29, # 46 p. 5917 - 5918]

A new efficient synthesis of β-aminoketones via Δ 4-isoxazolines.

[Mancuso, Vincent; Hootele, Claude Tetrahedron Letters, 1988 , vol. 29, # 46 p. 5917 - 5918]

Metabolism of N-alkyldiamines and N-alkylnortropinones by transformed root cultures of Nicotiana and Brugmansia

[Boswell, Henry D.; Draeger, Birgit; Eagles, John; McClintock, Carol; Parr, Adrian; Portsteffen, Andreas; Robins, David J.; Robins, Richard J.; Walton, Nicholas J.; Wong, Chi Phytochemistry, 1999 , vol. 52, # 5 p. 855 - 869]

A simple synthesis of isopelletierine: Research on the synthesis of compounds from the group of alkaloids from Punica Granatum 3rd communication

[Wibaut; Kloppenburg; Beets Recueil des Travaux Chimiques des Pays-Bas, 1944 , vol. 63, p. 136]

A simple synthesis of isopelletierine: Research on the synthesis of compounds from the group of alkaloids from Punica Granatum 3rd communication

[Wibaut; Kloppenburg; Beets Recueil des Travaux Chimiques des Pays-Bas, 1944 , vol. 63, p. 136]

More Articles...