Concerning the Formation, Hydrolysis and Thermolysis of Acyclic Phosphoranes

N Lowther, P Crook, D Hall

Index: Lowther, Nicholas; Crook, Polly; Hall, Dennis Phosphorus and Sulfur and the Related Elements, 1987 , vol. 30, p. 405 - 408

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Abstract

Abstract Kinetic data on the formation, hydrolysis and thermoly- sis of acyclic phosphoranes is reported and the mechanism of each reaction is discussed. ... INTRODUCTION The reaction of trico-ordinate phosphorus compounds (1) with sul- phenate esters (2) is now a well-established route to a wide range of phosphoranes (3 and 4)l. quantitative data to support the proposed mechanism of biphilic There is however, relatively little ... (4 1 insertion of (1) into the S-0 link of (2)'.

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