Solvation and steric effects on electrophilic reactivity of ethylenic compounds. 3. Stereo-, regio-, and chemoselectivity of alkene bromination in methanol

JR Chretien, JD Coudert…

Index: Chretien, Jacques R.; Coudert, Jean-Daniel; Ruasse, Marie-Francoise Journal of Organic Chemistry, 1993 , vol. 58, # 7 p. 1917 - 1921

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Citation Number: 24

Abstract

Results The products of brominating 30 mono-, di-, tri-, and tetrasubstituted alkenes in methanol containing 0.2 M sodium bromide were measured by GC analysis of the reaction mixture, without any workup after the end of bromine addition. The results collected in Table I were obtained at 25 OC by using experimental conditione very similar to those used for kinetic meas~ rements.~ The initial alkene concentration is M; electrochemically ...