Tetrahedron letters

Fluorination of α, α-dichlorosulfides: access to gem-difluorothioethers as useful building blocks

…, C Guérin, L Lemoucheux, T Lequeux, JC Pommelet

Index: Gouault, Sonia; Guerin, Cecile; Lemoucheux, Laurent; Lequeux, Thierry; Pommelet, Jean-Claude Tetrahedron Letters, 2003 , vol. 44, # 27 p. 5061 - 5064

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Citation Number: 12

Abstract

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The synthesis of alkylsulfanyldifluoro-acetate and ketones by the Halex reaction is described. The remarkable reactivity of thiodifluoroacetate derivatives opened rapid access for the preparation of useful building blocks such as gem-difluoroketones and amides.

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