Isolation and characterization of hydroformylation 'intermediates' from stoichiometric reactions between phosphinoalkenes and some heterobinuclear complexes

…, W áRoy Jackson, TD Simone, BW Skelton…

Index: Coutinho, Kevin J.; Dickson, Ron S.; Fallon, Gary D.; Jackson, W. Roy; De Simone, Tania; Skelton, Brian W.; White, Allan H. Journal of the Chemical Society - Dalton Transactions, 1997 , # 18 p. 3193 - 3199

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Citation Number: 19

Abstract

Some heterobimetallic acyl and µ-acyl-rhodium complexes have been isolated from reactions of the phosphido-bridged complexes (OC) 4M (µ-PPh2) 2RhH (CO)(PPh3) with the phosphinoalkenes Ph2P (CH2) nCH [[double bond, length as m-dash]] CH2 where M= Cr, Mo or W and n= 1–3. Several of the complexes have been fully characterized and their potential role a