Preparation, electrochemical oxidation, and XPS studies of unsymmetrical ruthenocenes bearing the pentamethylcyclopentadienyl ligand

PG Gassman, CH Winter

Index: Gassman,P.G.; Winter,C.H. Journal of the American Chemical Society, 1988 , vol. 110, p. 6130

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Citation Number: 128

Abstract

Abstract: The reaction of dichloro (pentamethylcyclopentadienyl) ruthenium (III) oligomer with alkali metal salts of a variety of cyclopentadienyl derivatives provided a convenient synthetic approach to unsymmetrical ruthenocenes. In addition, reaction of dichloro ( pentamethylcyclopentadienyl) ruthenium (III) oligomer with diazotetrachlorocyclopentadiene gave ($-pentamethylcyclopentadienyl)(q5-pentachlor~ yclo~ ntadienyl) ruthenium (II). ...