Organic Letters

Critical role of catalysts and boranes for controlling the regioselectivity in the rhodium-catalyzed hydroboration of fluoroolefins

PV Ramachandran, MP Jennings, HC Brown

Index: Ramachandran, P. Veeraraghavan; Jennings, Michael P.; Brown, Herbert C. Organic Letters, 1999 , vol. 1, # 9 p. 1399 - 1402

Full Text: HTML

Citation Number: 60

Abstract

Catalytic hydroboration of perfluoroalkylethylenes (RFCH CH2) with cationic and neutral rhodium complexes allows for selective access to either regioisomeric alcohol after hydroboration with catechol-and pinacolboranes, followed by oxidation with alkaline hydrogen peroxide.

Related Articles:

Investigation of the factors controlling the regioselectivity of the hydroboration of fluoroolefins

[Ramachandran, P. Veeraraghavan; Jennings, Michael P. Chemical Communications, 2002 , # 4 p. 386 - 387]

Réactivité des 1-F-alkyl-2-fluoroéthyl p-toluènesulphonates en milieu basique

[Hedhli, A.; Chaabouni, M. M.; Baklouti, A. Journal of Fluorine Chemistry, 1992 , vol. 56, # 2 p. 239 - 247]

Réactivité des 1-F-alkyl-2-fluoroéthyl p-toluènesulphonates en milieu basique

[Hedhli, A.; Chaabouni, M. M.; Baklouti, A. Journal of Fluorine Chemistry, 1992 , vol. 56, # 2 p. 239 - 247]

More Articles...