Energy partitioning in the reaction F+ I2

RJ Donovan, DP Fernie, MAD Fluendy, RM Glen…

Index: Donovan, R. J.; Fernie, D. P.; Fluendy, M. A. D.; Glen, R. M.; Rae, A. G. A.; Wheeler, J. R. Chemical Physics Letters, 1980 , vol. 69, p. 472 - 475

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Citation Number: 8

Abstract

Abstract The vibrational populations and rotational temperature of the IF product formed in the reaction F+ I 2→ IF+ I have been measured using a crossed-beam laser-induced fluorescence technique. The relative collision energy was 90 meV. Measurements of the relative populations in the υ= 0, 1 and 2 levels showed a strong population inversion with an effective temperature of− 3000 K, corresponding to a fraction of the total energy,< f υ>= 0.6 ...

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