Reactivity of Lithium Alkylamide toward Vinylsilane Derivatives.

Y Nagasaki, S Morishita, M Kato, Y Kihara…

Index: Nagasaki, Yukio; Morishita, Shinya; Kato, Masao; Kihara, Yasuharu; Tsuruta, Teiji Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 4 p. 949 - 953

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Citation Number: 6

Abstract

Kinetic studies concerning the addition reactions of lithium diethylamide (Et 2 NLi) to several vinylsilane derivatives, such as H 2 C= CH–Si (CH 3) 2 X [X: methyl, phenyl, ethoxy, 2- (diethylamino) ethyl and vinyl], and H 2 C= CH–Si (CH 3) 2 OSi (CH 3) 2 X [X: 2- (diethylamino) ethyl and vinyl], were carried out. The reactivity of vinylsilane derivatives toward nucleophile was strongly influenced by the nature of the substituents on the Si ...