Tetrahedron letters

Synthesis of 1, 3, 3-trinitroazetidine

T Axenrod, C Watnick, H Yazdekhasti, PR Dave

Index: Axenrod, Theodore; Watnick, Clara; Yazdekhasti, Hamid; Dave, Paritosh R. Tetrahedron Letters, 1993 , vol. 34, # 42 p. 6677 - 6680

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Citation Number: 38

Abstract

Abstract The t-butyldimethylsilyl ether of 3-(p-toluenesulfonamido) propane-2-ol-1-(p- toluenesulfonate) on treatment with LiH undergoes ring closure to the correponding azetidine which is readily converted to N-tosyl-3-azetidinone oxime. By oxidative nitrolysis the latter affords 1, 3, 3-trinitroazetidine.

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Synthesis of 1, 3, 3-trinitroazetidine via the oxidative nitrolysis of Np-tosyl-3-azetidinone oxime

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Synthesis of 1, 3, 3-trinitroazetidine via the oxidative nitrolysis of Np-tosyl-3-azetidinone oxime

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