Organic letters

cis-2, 5-Diaminobicyclo [2.2. 2] octane, a New Scaffold for Asymmetric Catalysis via Salen− Metal Complexes

JD White, S Shaw

Index: White, James D.; Shaw, Subrata Organic Letters, 2011 , vol. 13, # 9 p. 2488 - 2491

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Citation Number: 29

Abstract

A new C 2 symmetric salen scaffold based on cis-2, 5-diaminobicyclo [2.2. 2] octane has been synthesized that forms complexes with a wide range of metals. The chromium (III) complex is shown to catalyze the hetero-Diels− Alder reaction and the Nozaki− Hiyama− Kishi reaction with high efficiency and excellent stereoselectivity.

Asymmetric synthesis of (5S)-4-deoxy-5-C-(4-nitrophenyl)-L-threo-pentose and (5R)-5-C-(4-nitrophenyl)-L-arabinose

[Helliwell, Madeleine; Phillips, Iain M.; Pritchard, Robin G.; Stoodley, Richard J. Tetrahedron Letters, 1999 , vol. 40, # 49 p. 8651 - 8655]

cis-2, 5-Diaminobicyclo [2.2. 2] octane, a New Scaffold for Asymmetric Catalysis via Salen− Metal Complexes

Abstract

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