Tetrahedron letters

Indium-mediated consecutive 1, 2-shift reaction and regioselective allylation of vinyl epoxides

BK Oh, JH Cha, YS Cho, KI Choi, HY Koh, MH Chang…

Index: Oh, Byung Kyu; Cha, Joo Hwan; Cho, Yong Seo; Choi, Kyung Il; Koh, Hun Yeong; Chang, Moon Ho; Pae, Ae Nim Tetrahedron Letters, 2003 , vol. 44, # 14 p. 2911 - 2913

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Citation Number: 20

Abstract

The use of organometallic reagents for organic synthetic purpose has been growing in scope and in importance. 1., and In particular, organoindium reagents have attracted much attention due to their compatibility with many common organic functional groups and stability under aqueous conditions. Allyl indium reagents, generated in situ from indium metal with activated halide (eg allyl halide, α-halo ester) in organic solvent is known to be sesquihalide, 2 (allyl) 3 In 2 X ...

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