Titanium (IV) aryloxide catalyzed cyclization reactions of 1, 6-and 1, 7-dienes

S Okamoto, T Livinghouse

Index: Okamoto, Sentaro; Livinghouse, Tom Journal of the American Chemical Society, 2000 , vol. 122, # 6 p. 1223 - 1224

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Citation Number: 55

Abstract

Transformations of unsaturated compounds mediated by stoichiometric quantities of zirconocene or titanocene complexes have received widespread acceptance as valuable methods in organic synthesis, and have been used as key reactions for the total synthesis of natural products. 2 Recently, the generation and subsequent utilization of low-valent complexes of the type (RO) 2Ti (L) n as alternatives to Cp2M (L) n (M) Ti, Zr) in many ...

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