Tetrahedron

Mg-promoted reductive coupling of aromatic carbonyl compounds with trimethylsilyl chloride and bis (chlorodimethylsilyl) compounds

T Uchida, Y Kita, H Maekawa, I Nishiguchi

Index: Uchida, Tetsuro; Kita, Yoshio; Maekawa, Hirofumi; Nishiguchi, Ikuzo Tetrahedron, 2006 , vol. 62, # 13 p. 3103 - 3111

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Citation Number: 8

Abstract

Mg-promoted reductive coupling of aromatic carbonyl compounds () with chlorosilanes, such as trimethylsilyl chloride (TMSCl:), 1, 2-bis (chlorodimethylsilyl) ethane () and 1, 5- dichlorohexamethyltrisiloxane (), in N, N-dimethylformamide (DMF) at room temperature brought about selective and facile reductive formation of both of carbon–silicon and oxygen– silicon bonds to give the corresponding α-trimethylsilylalkyl trimethylsilyl ethers () and ...

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