Fluorocyclopropanes. II. Synthesis, properties, and reactions of perfluorocyclopropene

PB Sargeant, CG Krespan

Index: Sargeant,P.B.; Krespan,C.G. Journal of the American Chemical Society, 1969 , vol. 91, # 2 p. 415 - 419

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Citation Number: 56

Abstract

Abstract: Perfluorocyclopropene has been prepared by the dehydrohalogenation of pentafluorocyclopropane and l-chloro-l, 2, 2, 3-tetrafluorocyclopropane and most conveniently by the dehalogenation of 1, 2-dichloro-l, 2, 3, 3-tetra-fluorocyclopropane. Perfluorocyclopropene is a flammable, explosive gas. It is surprisingly stable to many conditions, but reacts with nucleophiles, water, and antimony pentafluoride. A Diels-Alder ...

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