Evidences for an efficient demethylation of methoxyellipticine derivatives catalyzed by a peroxidase

G Meunier, B Meunier

Index: Meunier, Gerard; Meunier, Bernard Journal of the American Chemical Society, 1985 , vol. 107, # 8 p. 2558 - 2560

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Citation Number: 31

Abstract

Iionic I 1 PHOTODI SSOClATlON and the substitution takes place via an ion pair as the intermediate analogous to other systems, studied by McCullough, I2 Arr~ old,'~ and Lewis, I4 one should expect a dependence of the mode selectivity on the electron transfer enthalpies AG. These AG values can be easily calculated by means of the Rehm-Weller eq~ ation.'~ A simplified version of this equation for 1, 4-dioxane (dielectric constant, c 2.2) as solvent is ...