THE EFFECT OF ADDED LITHIUM CATIONS ON THE STEREOCHEMISTRY OF NUCLEOPHILIC DISPLACEMENT REACTIONS AT PHOSPHORUS

CR Hall, TD Inch, C Pottage

Index: Hall, C. Richard; Inch, Thomas D.; Pottage, Colin Phosphorus and Sulfur and the Related Elements, 1981 , vol. 10, p. 229 - 232

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Abstract

Abstract Added lithium cation has no effect on the stereochemical outcome of the displacement of chloride or p-nitrophenoxide from phosphorus in acyclic and some cyclic molecules. In other cyclic systems the preponderant stereochemistry can be biased from inversion to retention of configuration.