Metal-stabilized phenoxonium cation

…, TS Koblenz, Y Ben-David, H Rozenberg…

Index: Vigalok, Arkadi; Rybtchinski, Boris; Gozin, Yael; Koblenz, Tehila S.; Ben-David, Yehoshoa; Rozenberg, Haim; Milstein, David Journal of the American Chemical Society, 2003 , vol. 125, # 51 p. 15692 - 15693

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Citation Number: 42

Abstract

An unprecedented metal-stabilized phenoxonium cation was prepared by a process involving dearomatization of a phenoxy complex. The unique η2 C O-metal (iridium) coordination mode leaves the positive charge delocalized within the former aromatic ring. The X-ray structure and conversion into η2 C O-coordinated metal-quinone complex are described.

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