Reaction of singlet oxygen with nitronate salts. Conversion of nitro compounds into carbonyls

JR Williams, LR Unger, RH Moore

Index: Williams,J.R. et al. Journal of Organic Chemistry, 1978 , vol. 43, p. 1271 - 1272

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Citation Number: 20

Abstract

(3). A mixture of 1 (4.10 g, 11.1 mmol) and tetramethylguanidine (2.39 g, 22.3 mmol) in 30 mL of anhydrous dimethylformamide was stirred in an ice bath. T,, the colti reaction mixture was added dropwise and simultaneously tert-butyloxycarbonyl azide6 (2.90 g, 22.3 mmol) and tetramethylguanidine (2.39 g, 22.3 mmol). The mixture was stirred